Premium is NOT more combustable, it's the opposite. Regular unleaded is more combustable than premium. During light throttle driving (highway driving for example) lower octane fuel will burn more completely whereas high octanes will have more unburnt fuel left behind, this is where a multiple spark helps out. It's moreso in a forced induction car becuase during light throttle driving you will be in vacuum and in really low compression (as most forced induction car's have lower compression than NA's). You raise the compression up, the fuel may burn more completely, but at the risk of preignition. This is where a higher octane helps to prevent this. You do not get added power from higher octane unless you have tuned for it.