It'll probably be OK. Consider this though: if the cap were sealed in the opposite direction the vacuum generated in the tank would collapse it. The tank collapses with this small delta P across it because of the surface area involved. The thing is that would happen at a delta much less than 14.7 psi, since that's the maximum achievable (at least on this planet), and there is no way the tank could get near that maximum by having fuel withdrawn from it.
Pressuring the tank is the same thing except the structural aspects of it may be weaker when the situation is reversed. Circular or near circular forms are always stronger in compression than tension. Think of crushing an egg versus the other way around. Even if the tank's form factor is not subject to this it's still going to feel the same force. I guess the real question is would you be comfortable pumping the tank to 10-12 psi with an air compressor. Or that worst case 25 psi.
Will the pressure ever get that high? I dunno. Since the car uses a fuel return type system they'll be heating of the fuel by that in addition to what's done by the ambient, pump, ect. Stock the tank is regulated to + 2 psi by the evap system. In your case it'll be free to do as it likes. I'd be worried about repeatably bulging the tank and the fatigue associated with that. Course, this is all theory. Try it and let us know.
Edit: On second thought the tank is steel. As long as it remains within the elastic limit there should be no fatigue so forget that part.