The majority of the connections in the diagnostic block are test points which intercept ECU signals (E1, OX1, OX2 TE1, VF1, +B, FP), others include the ECT system (the TT contact), TEMS (TS)... See the TEWD for more info.
http://www.cygnusx1.net/Supra/Library/TEWD/MK3/manual.aspx?Section=Main&Page=48
E1 is ,more specifically, the TCCS' Computer ground (BTW, E2 is the TCCS' sensor ground). +B and +B1 are both 12v supplies from the EFI main relay. VF1 represents the TCCS'
VF diagnostic signal (this operates in 3 different modes), FP is a test
feed to the fuel pump (bypasses protection circuitry and the relay and resistor pack)..... yada, yada, yoda....
How you use the diagnostic block varies from one circuit to the next. The TSRM covers when and how to test each circuit.
Here's a HINT; Go to the last page of each section of the TEWD and look for the following among the connector diagrams:
This will show you if the circuit in question has a connection to the diagnostic block.
Oh and by the way, it doesn't hurt to replace the old dielectric grease with some fresh dielectric grease. I know mine was no longer up to the task.