After a certain RPM the wheel just doesn't catch air, do any of you people posting over 25psi know how a centrifugal impeller works?
Centrifugal impellers cant suck in air very well they use centrifugal force to PUSH air. Air in front of the blades is caught by the tip of the spinning impeller, witch is then (via centrifugal force) thrown or pushed to the outside of the compressor housing. the air being thrown/pushed to outside of the housing hits the air thats already contained in the housing, pushing it wherever it will go with least resistance (the outlet) into the intercooler piping. The air being pushed out of the housing creates the only amount of vacuum or area of low pressure in front of the impeller. Its a siphon effect of air moving out, drawing air in.
The comes a speed or RPM where the impeller is turning so fast that air just cant be caught by the impeller due to most likely either turbulence or just because air cant move fast enough to be effectively captured by the fins, sending efficiency to the toilet because having air to move is what they rely on to move air.
Ever notice if you put your hand over the hose of a vacuum cleaner the motor speeds up? its the same type of centrifugal impeller, though obviously designed to push a lot of air creating a lot of vacuum. when you put your hand over the hose, you are taking away the air supply to the impeller. without an air supply the impeller looses efficiency since it no longer has any air in front of the fins to be captured. Since there is no air being captured by the fins there is less resistance on the electric motor creating the increase in RPM.
On the other hand and i don't recommended trying this, a piston or positive displacement pump (engine) doesn't rely on this supply and will create as much vacuum as the motor driving it and seals sealing it can supply, and Diesels can actually break your hand or hyper extend your fingers if you put it over an intake pipe. piston pumps will slow down when restriction to intake is applied because there is more resistance to move.
The smallest intake restriction can totally destroy the efficiency of a turbo, thats why nice large low restriction intakes are always fitted to turbocharged cars rather then ones that are just big enough to work. same with exhaust because the same basic principals apply but thats more about pressure ratios, thats another subject.
And finally, Boost by itself has no relation to flow or horsepower, boost is resistance to flow nothing more. You can boost more and flow less because temperature influences the density of air greatly.
/Long post.