A little electrical humor there.
First off, if you're not sure of where something goes use a fused jumper to connect it. One of those cheap inline fuseholders with a 10 amp fuse in it will do. That way the only damage will be a blown fuse. Second, all the hot wires in the car come from the battery positive. If you know the wire is already hot connecting it there won't cause anything to happen. It's the same point electrically. Lastly, the wire you've been puzzled about looks to be your Alternator B+ line. That's why I said not to ground it. Easy enough to tell just by looking at the alternator...
First off, if you're not sure of where something goes use a fused jumper to connect it. One of those cheap inline fuseholders with a 10 amp fuse in it will do. That way the only damage will be a blown fuse. Second, all the hot wires in the car come from the battery positive. If you know the wire is already hot connecting it there won't cause anything to happen. It's the same point electrically. Lastly, the wire you've been puzzled about looks to be your Alternator B+ line. That's why I said not to ground it. Easy enough to tell just by looking at the alternator...