a post from before i think this is what you are talking about.
http://www.supramania.com/forums/showthread.php?t=2557
" OK, people. Toyota (and other cars too) had a problem in the 80's with what is called "a hard start problem after sitting for a couple of hours" (actually I can't remember the real name).
Main cause: the intake valves have built up carbon deposits on the back sides. When the car sits (off) for a while, the fuel that has soaked into this carbon (like a sponge) evaporates away. Now when you go to start the car, this carbon soaks up the initial fuel coming in. (injectors spray it right on them) Thats why it will usually start the 2nd or 3rd attempt, because they have soaked up enough fuel (sponge is full) to let a full charge of fuel into the combustion chamber.
Todays solution......go to a shop and have what is called an "air induction system flush (cleaning)". They will use some very strong cleaner with their equipment, and ad a very strong fuel additive to the tank.
After that, the best tank additive is called Techron (black bottle, made by Chevron). Auto parts stores and Walmart sell it. Use as directed, on a couple of tanks. "